Controlling Horizontal Dipole Orientation and Emission Spectrum of Ir Complexes by Chemical Design of Ancillary Ligands for Efficient Deep‐Blue Organic Light‐Emitting Diodes

Deep‐blue emitting Iridium (Ir) complexes with horizontally oriented emitting dipoles are newly designed and synthesized through engineering of the ancillary ligand, where 2′,6′‐difluoro‐4‐(trimethylsilyl)‐2,3′‐bipyridine (dfpysipy) is used as the main ligand. Introduction of a trimethylsilyl group at the pyridine and a nitrogen at the difluoropyrido group increases the bandgap of the emitter, resulting in deep‐blue emission. Addition of a methyl group (mpic) to a picolinate (pic) ancillary ligand or replacement of an acetate structure of pic with a perfluoromethyl‐triazole structure (fptz) increases the horizontal component of the emitting dipoles in sequence of mpic (86%) > fptz (77%) > pic (74%). The organic light‐emitting diode (OLED) using the Ir complex with the mpic ancillary ligand shows the highest external quantum efficiency (31.9%) among the reported blue OLEDs with a y‐coordinate value lower than 0.2 in the 1931 Commission Internationale de L'Eclairage (CIE) chromaticity diagram.     

Making Large‐Area Titanium Disulfide Films at Reduced Temperature by Balancing the Kinetics of Sulfurization and Roughening

The synthesis of large‐area TiS₂ thin films is reported at temperatures as low as 500 °C using a scalable two‐step method of metal film deposition followed by sulfurization in an H₂S gas furnace. It is demonstrated that the lowest‐achievable sulfurization temperature depends strongly on the oxygen background during sulfurization. This dependence arises because Ti? O bonds present a substantial kinetic and thermodynamic barrier to TiS₂ formation. Lowering the sulfurization temperature is important to make smooth films, and to enable integration of TiS₂ and related transition metal dichalcogenides—including metastable phases and alloys—into device technology.     

Biogenic amine production of makgeollis with controlled alcohol concentrations

Food Science and Biotechnology - In this study, we examined the effects of controlling the alcohol concentration of non-sterilized makgeolli on the levels of biogenic amines (BAs) as an indicator...     

Low cycle fatigue behavior of hot-bent 347 stainless steel in a simulated PWR water environment

The effect of hot bending on the Low cycle fatigue (LCF) behavior of 347 SS was evaluated in Room temperature (RT) air and simulated Pressurized water reactor (PWR) water environments. The LCF life of 347 SS in PWR water was shorter than that in RT air for the as-received and hot-bent conditions. The LCF life of hot-bent 347 SS was relatively longer than that of the as-received condition in both RT air and PWR water. Microstructure analysis indicated development of dislocation structure near niobium carbide particles and increase in dislocation density for the hot-bent 347 SS. Such microstructure acted as barriers to dislocation movement during the LCF test, resulting in minimal hardening for the hot-bent 347 SS in RT air.